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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Styrene monooxygenase ： ウィキペディア英語版 Styrene monooxygenase A styrene monooxygenase (SMO; EC 1.14.14.11) is an enzyme that catalyzes the chemical reaction :styrene + FADH2 + O2 ↔ (''S'')-2-phenyloxirane + FAD + H2O as the first step of the aerobic styrene degradation pathway.〔Mooney, A., P. G. Ward, and K. E. O'Connor. 2006. Microbial degradation of styrene: biochemistry, molecular genetics, and perspectives for biotechnological applications. Appl. Microbiol. Biotechnol. 72:1-10. (16823552 )〕 The product 2-phenyloxirane is also known as styrene oxide and can be converted by a styrene oxide isomerase (SOI) to obtain phenylacetaldehyde, which can be transformed into the key-intermediate phenylacetic acid by a phenylacetaldehyde dehydrogenase (PAD). The enzyme belongs to the group of oxidoreductases according EC classification and is dependent on FAD as cofactor, thus it was classified as an external flavoprotein monooxygenase (designated as type E).〔Montersino, S., D. Tischler, G. T. Gassner, and W. J. H. van Berkel. 2011. Catalytic and structural features of flavoprotein hydroxylases and epoxidases. Adv. Synth. Catal. 353:2301-2319.〕〔van Berkel, W. J. H., N. M. Kamerbeek, and M. W. Fraaije. 2006. Flavoprotein monooxygenases, a diverse class of oxidative biocatalysts. J. Biotechnol. 124:670-689. (16712999 )〕 It forms a two-component system with a reductase (StyB, StyA2B). The reductase utilizes solely NADH to reduce the FAD, which is then transferred to the styrene monooxygenase (StyA, StyA1). Two types of that enzyme are described so far: StyA/StyB (designated E1), first described from ''Pseudomonas'' species, and StyA1/StyA2B (designated E2), first described from Actinobacteria. The E1-type is more abundant in nature and comprises a single monooxygenase (StyA) supported by a single reductase (StyB), whereas the E2-type has a major monooxygenase (StyA1) which is supported by fusion protein of a monooxygenase and reductase (StyA2B). The latter one is the source of reduced FAD for the monooxygenase subunits and has some side activity as a monooxygenase. So far all styrene monooxygenases perform enantioselective epoxidations of styrene and chemically analogous compounds, which makes them interesting for biotechnological applications.〔 ==References== 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Styrene monooxygenase」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.